cis-1-Benzylpyrrolidine-2,5-dicarbonitrile

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cis-1-Benzyl­pyrrolidine-2,5-dicarbonitrile

In the title compound, C(13)H(13)N(3), the cyano groups at the 2- and 5-positions are eclipsed with each other. The phenyl ring is disordered over two sets of sites, with refined occupancies of 0.520 (5) and 0.480 (5). The angles between the mean plane of the pyrrolidine ring and the two cyano groups are 71.7 (9) and 75.0 (12)°.

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1-(2-Cyano­eth­yl)-1H-imidazole-4,5-dicarbonitrile

In the title tricyano-nitrile compound, C(8)H(5)N(5), the N-substituted cyano-ethyl group is offset to the imidazole ring [dihedral angle = 75.41 (15)°].

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3-Amino-1-(3,4-dimeth­oxy­phen­yl)-9,10-dihydro­phenanthrene-2,4-dicarbonitrile

In the title compound, C(24)H(19)N(3)O(2), the partially saturated ring adopts a distorted half-chair conformation with the methyl-ene-C atom closest to the amino-benzene ring lying 0.664 (3) Å out of the plane defined by the five remaining atoms (r.m.s. deviation = 0.1429 Å. The dihedral angle [32.01 (10)°] between the benzene rings on either side of this ring indicates a significant fold in t...

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3-Amino-1-methyl-9,10-dihydro­phenanthrene-2,4-dicarbonitrile

The asymmetric unit of the title compound, C(17)H(13)N(3), contains two independent mol-ecules, which are non-planar as they are buckled owing to the ethyl-ene portion. The dihedral angle between the benzene rings is 26.4 (1)° in one mol-ecule and 32.9 (1)° in the other. In the crystal, the mol-ecules are disposed about a false inversion center, and are linked by two N-H⋯N hydrogen bonds, gener...

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3-Amino-1-(thio­phen-2-yl)-9,10-dihydro­phenanthrene-2,4-dicarbonitrile

In the title compound, C(20)H(13)N(3)S, the partially saturated ring adopts a twisted half-boat conformation with the methyl-ene C atom closest to the amino-benzene ring lying 0.690 (6) Å out of the plane defined by the five remaining atoms. The dihydro-phenanthrene residue has a folded conformation [dihedral angle between the outer benzene rings = 26.27 (18)°]. The thio-phen-2-yl ring forms a ...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811006258